Deeper insights into 2D-Materials and related Microcrystals by Imaging Spectroscopic Ellipsometry (ISE) and Imaging Mueller Matrix Ellipsometry (IMME)
SPEAKERS
  • Peter H. Thiesen
    Application Specialist ISE, ISE Support, Park Systems GmbH
Authors
Peter H. Thiesen

Imaging Spectroscopic Ellipsometers (ISE) combine the benefits of ellipsometry and optical microscopy in a single device. The unification of the two technologies creates a unique metrology tool that redefines the limits of both ellipsometric measurements and polarization-contrast microscopy. The enhanced spatial resolution of imaging ellipsometers expands ellipsometry into new areas of microanalysis, microelectronics, and bio analytics. Imaging Ellipsometry is an all-optical, non-contact metrology technique that excels at the layer-thickness and material characterization of micro-structured thin-film samples and substrates.
In the field of 2D materials characterization, Imaging Spectroscopic Ellipsometry enable the determination of optical properties [1],[2],[3].. The data are required for a better understanding of 2D material based devices [4],[5]..
From the macroscopic point of view, ellipsometric contrast micrographs or microscopic maps of Delta and Psi can be stitched and offer a fast, non-contact, wafer-scale, atomic layer resolved imaging of 2D materials [6] on a variety of substrates. Including maps recorded at different wavelengths, a specific search for microcrystals with a dedicated number of layers or a predefined thickness was reported. Recent studies also show the possibility of imaging buried layers [7].
The focus of the talk will be on applications of Imaging Müller matrix ellipsometry for anisotropic microcrystals characterization. Micrographs of 11 elements of the Müller Matrix, normalized to element 1 were recorded at different wavelength and orientations for different microcrystals like Black Phosphorous or Bi2SeO5 (Fig, 1).

 

2d_materials_characterization_with_ISE_and_IMME.png

Figure 1: Microscopic Maps of 11 elements of the Müller Matrix (a), the element m23 in detail (b) and rotated (c) of a Bi2SeO5 microcrystals on SiO2 | Si substrate.
 
 
References:
[1] S. Funke et al., J. Phys.: Condens. Matter 28 (2016) 385301.
[2] G.A. Ermolaev et al., Nat Commun 12 (2021), 854.
[3] P. G. Zotev et al., Laser Photonics Rev. 17 (2023), 2200957
[4] S. R. Tamalampudi et al., npj 2D Materials and Applications 8 (2024) 46.
[5] Dushaq, G. et al., Light Sci Appl 13, (2024) 92.
[6] P. Braeuninger-Weimer et al., ACS Nano 12, (2018) 8555–8563.
[7] Irina Chircă et al., 2D Mater. 11 (2024) 045001